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EPR電子順磁共振儀耗材 Miscellaneous EPR Supplies

EPR電子順磁共振儀耗材
Impurity Analyses – Clear Fused Quartz (CFQ) vs. Suprasil (Synthetic Quartz) 
EPR Sample Tubes and Accessories
EPR Cells
Dewar Inserts
Dewar Flasks (Cold-Finger Dewars)
Variable Temperature Accessories
Electrolytic Cells for EPR
‧ Miscellaneous EPR Supplies

Miscellaneous EPR Supplies
•Sample Handling Accessories
•EPR/NMR Tube Caps
•NMR/EPR Tube Racks
•NMR/ EPR Tube Labels
•NMR/EPR Tube Tip-off Manifold
•pH Electrode and Connectors

Sample Handling Accessories

Stainless Steel EPR Spatula

Handling powder samples is easy with the right tool; getting a tiny sample into a 5mm EPR tube should never be a struggle again. Unlike ordinary spatulas, our SST version fits into the most common EPR tubes. Add or remove samples easily; scoop samples with the round end, or pry stiff samples with the sharp-edged flat end. Freeze-dry your samples right in the tube because now they’re so easy to remove.

Many of our customers love this valuable tool. Order yours today!

Pipets – Manufactured By Wilmad-LabGlass

Use our NMR pipets for your EPR work as well for easy addition or removal of liquid samples from your EPR sample tube.

• Economical – compared to replacing EPR tubes broken using the wrong tools.

• Designed to reach the bottom of the longest EPR sample tube.

• Packaged conveniently in packs of 100.

• Two sizes are available to accommodate your tube length.

**Don’t forget to order your latex rubber pipet bulbs (804).

Note: Not recommended for heavy-walled NMR tubes.


Latex NMR
Pipet Bulb

 

 
Additional Pipets and Accessories

EPR Filters and Funnel
Our Sintered Glass EPR Sample Filters remove suspended particles 60 microns in diameter or larger.

Hamilton Gas-Tight Syringes
Gas-tight and inert, these specially selected Hamilton syringes are ideal for EPR sample handling. Use with stainless steel or Teflon needles.

Stainless Steel Needle
Needles are 2 inches long and have a beveled point. Ask customer service about longer needles.

NMR/EPR Tube Caps – Disposable


Disposable Tube Caps are manufactured from molded Ethylene Vinyl Acetate* or Polyethylene depending on the tube OD. The different colors help track samples based on various reference solvents.

Our popular 5mm size is available in eight colors.

New 5mm Polyethylene Cap for Automated Systems.

Packaged in bags of 100 or 1000 except where noted.


*Technical Tips:Please avoid using disposable NMR caps when CDCI3serves as the reference solution as the material(s) could be dissolved. When using CDCI3, we recommend PTFE caps (WG-1264-) which are only compatible with our Precision tubes.

**Replacement cap with hole for WGS-5BL.

***Cap for Automatic Sampling Systems; 5mm Tube.

Automated Handling Cap
NMR/EPR Tube Caps – PTFE

 

 

 

Pictured on tube

Our PTFE NMR/EPR Tube Caps are machined to exact specifications with smaller gyroradius and more homogeneous mass distribution than disposable caps providing better spinning stability. They are recommended for experiments at high – ultra high field and those using Chloroform as the reference solution. They will only fit our Precision tubes due to the tight tolerance.

NMR/EPR Tube Caps – Gas-Tight

Our Gas-Tight Tube Caps are ideal for experiments that require an air-tight environment under vacuum or low pressure less than 1 bar. Use with our Medium-Walled and Heavy-Walled NMR tubes for better seal and robustness in variable temperature experiments.

Serum Caps allow easy access via syringe needle.

NMR/EPR Tube Racks

Three styles available for our NMR and EPR Tubes
820-A
Lightweight polypropylene rack maximizes your benchtop storage capacity and is virtually inert.
WG-1301
Coated steel rack is completely encased in inert polyvinylchloride.

WG-2442
Stainless Steel Rack.

Pressure Sensitive NMR/EPR Tube Labels

These labels are a handy alternative to marking your NMR or EPR sample tubes. Each fits the circumference of the tube precisely with no overlapping to guarantee symmetry in spinning experiments.

NMR/EPR Tube Tip-off Manifold

How to make sealing your NMR/ EPR tubes easy!
If you struggle preparing NMR/EPR samples of air-sensitive mixtures, there is a simpler way! Use our NMR/EPR Tube Tip-off Manifold. You’ll find vacuum transfers, freeze-pump-thaws and sample sealing easy to complete. Fuse the manifold port quickly to your vacuum rack. The chemical resistance is excellent, only Viton®, Teflon®and Pyrex®come in contact with your sample. Tube connects to a threaded aluminum bushing isolated from the vacuum by a Teflon high-vacuum rotary valve. A twist of the wrist opens and closes both the rotary valve and port bushing.

pH Electrode and Connectors

Does your pH electrode fit into 5mm tubes? Most aren’t small enough to fit even a 10mm EPR tube. Not ours! The Combination pH Electrode for NMR/EPR Tubes fits easily into our thin wall 5mm EPR tube (e.g. 703-PQ).

It’s the only electrode your lab will ever need. It’s so versatile, it works for nearly all pH measurements.

pH Electrodes

Electrode Reference Solutions and Cleaners

EPR電子順磁共振儀耗材 Electrolytic Cells for EPR

EPR電子順磁共振儀耗材
Impurity Analyses – Clear Fused Quartz (CFQ) vs. Suprasil (Synthetic Quartz)     
EPR Sample Tubes and Accessories     
EPR Cells    
Dewar Inserts     
Dewar Flasks (Cold-Finger Dewars)     
Variable Temperature Accessories     
‧ Electrolytic Cells for EPR  
Miscellaneous EPR Supplies     

Electrolytic Cells for EPR
•Wilmad’s Electrolytic Cell Assemblies
•Components for Wilmad’s Electrolytic Cell Assembly
•Electrode Reference Solutions and Cleaners

Wilmad’s Electrolytic Cell Assemblies

Study electrolytically generated radicals in aqueous solutions.

Avoid alkali metal reductions, the associated sample sensitivity to air or moisture and background signals! Never deal with a high vacuum apparatus again!

The electrochemical or coulometric generation of radicals in aqueous media has been employed successfully for years. It’s ideal for biological samples because of the control afforded by voltaic methods. Just connect Wilmad’s Electrolytic Cell to a potentiostat.

Controlled oxidation-reduction reactions can be carried out right in the EPR cavity! A complete cell includes two Calomel Reference Electrodes, a pair of Platinum Electrodes, and a gas bubbler for deoxygenation. Wilmad provides the Electrolytic Cell Assembly as a complete unit with CFQ or Suprasil®Flat Cell, or you can order components separately. Electrolytic cells are available for the TE102or TE011cavities of all spectrometers.

Components:

Flat Electrolytic Cells have two10/30 outer joints, one for the Gas Bubbler and one Platinum Electrode at the top and a single5/20 outer joint at the bottom for the other Platinum Electrode. The flat section is either CFQ or Suprasil. The remainder of the Flat Cell is CFQ. You need a minimum of 15mL of sample solution to make contact with the electrodes and gas bubbler. The cell width for JEOL spectrometers is 10mm outside; product number WG-810-J-A (-Q). For all other spectrometers, the cell width is 10.5mm outside, product number WG-810-A (-Q).

The Gas Bubbler Assembly is a three-piece Pyrex chamber which holds part of your sample. It has three10/30 outer joints at the top for the Gas Bubbler and two Calomel Electrodes. The lower10/30 inner joint fits into the top of the Flat Electrolytic Cell. Nitrogen should be bubbled through the solution before and during your experiment to remove paramagnetic oxygen and mix the sample during electrolysis; product numbers WG-810-B-1, WG-810-B-2, WG-810-G.

Platinum Electrodes are prepared using 0.016″ (0.4mm) diameter wire. The upper electrode, WG-810-C, uses 8″ (203mm) of platinum and acts as the working electrode in oxidation reactions. The lower electrode, WG-810-D, has only 2″ (50mm) of platinum and acts as the auxiliary electrode in oxidation reactions. If you add a few drops of mercury to the cell, the lower electrode can be used as the working cathode in reduction reactions. Each Platinum Electrode incorporates a Pt-to-W weld. The tungsten (W) external wire lets you quickly clip your potentiostat leads to the electrode.

Electrolysis Limits in Water (vs. Saturated Calomel Electrode)

Calomel Electrodes are included in two lengths, one 13″ (330mm) and the other 83/4” (222mm). Connect your potentiostat to the half cell at a tungsten wire that penetrates the electrode wall. Add mercury in the outer chamber to a height that makes contact with the tungsten lead. Each electrode provided with a stopper. Not supplied with mercury. Electrolytes sold separately.

Wilmad Electrolytic Cell Assemblies

TIP: An electrolytic cell designed by Prof. Robert Allendorfer of SUNY, Buffalo and sold by Bruker Instruments offers improved sensitivity using a cylindrical TM110cavity. Its use is recommended when sample sensitivity is low.

Remember: Wilmad uses “-Q” to designate versions using Suprasil in the critical portions of the cell. All other cells are prepared from Clear Fused Quartz (CFQ).

Components for Wilmad’s Electrolytic Cell Assembly

Please note: Items marked “CALL” are custom manufactured – please contact Customer Service for single piece or lot pricing.

Flat Electrolytic Cells
These cells have two10/30 outer joints, one for the Gas Bubbler and one Platinum Electrode at the top and a single5/20 outer joint at the bottom for the other electrode. The flat section is either CFQ or Suprasil. The remainder of the Flat Cell is CFQ. A minimum of 15mL of sample solution to make contact with the electrodes and gas bubbler. The cell width for JEOL spectrometers is 10mm outside. For all other spectrometers, the cell width is 10.5mm outside.

Gas Bubbler Assembly
A three-piece Pyrex chamber which holds part of your sample. It has three10/30 outer joints at the top for the Gas Bubbler and two Calomel Electrodes. The lower10/30 inner joint fits into the top of the Flat Electrolytic Cell. Nitrogen should be bubbled through the solution before and during your experiment to remove paramagnetic oxygen and mix the sample during electrolysis.

Platinum Electrodes
Prepared using 0.016″ (0.4mm) diameter wire. The upper electrode, WG-810-C, uses 8″ (203mm) of platinum and acts as the working electrode in oxidation reactions while the lower electrode, WG-810-D, has only 2″ (50mm) of platinum and acts as the auxiliary electrode. Adding a few drops of mercury to the cell allows the lower electrode to function as the working cathode in reduction reactions. Each Platinum Electrode incorporates a Pt-to-W weld. The tungsten (W) external wire lets you quickly clip your potentiostat leads to the electrode.

Calomel Electrodes
Supplied in two lengths, one 13″ (330mm) and the other 83/4” (222mm). Connect your potentiostat to the half cell at a tungsten wire that penetrates the electrode wall. Add mercury in the outer chamber to a height that makes contact with the tungsten lead. Each electrode is provided with a stopper.

Remember: Like many Quartz products for EPR, Electrolytic Cell components can often be repaired for costs that are less than new components. Contact Customer Service to ask about this service.

Electrode Reference Solutions and Cleaners

Calomel Reference Electrodes utilize a 3M potassium Chloride (KCl) solution saturated with Silver Chloride (AgCl). Use it to fill or replace reference solution in any pH or other electrode which incorporates a Calomel Reference.

In addition, we provide cleaning solutions which can be used to remove specific surface contaminants from your reference electrode junction.

EPR電子順磁共振儀耗材 Variable Temperature Accessories

EPR電子順磁共振儀耗材
Impurity Analyses – Clear Fused Quartz (CFQ) vs. Suprasil (Synthetic Quartz)     
EPR Sample Tubes and Accessories    
EPR Cells    
Dewar Inserts   
Dewar Flasks (Cold-Finger Dewars)     
‧ Variable Temperature Accessories  
Electrolytic Cells for EPR     
Miscellaneous EPR Supplies     

Variable Temperature Accessories
Replacement Parts for VT Systems

Need a replacement component for your variable temperature system?
Since Wilmad offers VT replacement components at prices significantly lower than the Original Equipment Manufacturer (OEM), why pay more? Wilmad components are equivalent or, in some cases, better in quality than you get from your EPR Spectrometer manufacturer.

You’ll get the best performance possible with Wilmad transfer dewars. Most are silvered for maximum thermal insulation. Where it has been possible, Wilmad transfer dewars are fully vacuum-jacketed, right to the end of socket and ball joints, so you get the most stable temperatures.
Bruker VT Transfer Dewar
The Bruker ER 4121 VT Variable Temperature System includes a long transfer dewar and a heater that goes inside it. The diameter and length of the heater and the transfer dewar has varied over the years, so choosing the right size dewar for your system was a real challenge.
Wilmad has made replacing the transfer dewar simple, though. Working closely with Bruker, we’ve developed two designs which work with all Bruker VT systems. The long version, WG-842-MX, works with all Bruker EPR spectrometers with magnets > 18 cm diameter. The shorter one works with all smaller magnets.

Wilmad’s versions of these transfer dewars are better than Bruker’s. We add a hollow ball joint for better thermal stability.

Only Wilmad makes a replacement for Varian’s E-257 Immersion Transfer Dewar!

Fully compatible with Varian’s E-257 VT System, this Immersion Transfer Dewar, Wilmad’s product number WG-760, incorporates a Kovar flange that fits the heat exchanger. It works better than the original transfer dewar of your VT System because it connects to the elbow transfer dewar through a jacketed socket.

This Elbow Transfer Dewar is better than the original you got from Varian!

You’ll get better performance with Wilmad’s WG-840 series of Elbow Transfer Dewars. That’s because we’ve redesigned the dewar to include a jacketed ball joint, so your cold carrier gas stays cold! No frosting!

It’s made with hooks that let you firmly hold the ball in the socket of the immersion transfer dewar (Wilmad’s product number WG-760) with springs.

You won’t need to rearrange your laboratory, either. Wilmad’s Elbow Transfer Dewars are available in three lengths, so you can choose the one that’s best for your setup. Call us for custom lengths.

Our special transfer dewar makes your VT setup more versatile!

Is the height of your replacement or new Nitrogen Evaporator Dewar too high or short for your VT setup? No problem. Wilmad has a solution. Our Bridge Transfer Dewar, WG-843, makes adjusting the flow path of your VT carrier gas easy!

Ideal for Bruker VT systems. Just turn the Evaporator Dewar Head around, place the Bridge Transfer Dewar between your long transfer and the Evaporator Dewar, and you cover the new angle.

This special transfer dewar can save you money and headaches. No custom manufacturing charges for a specially designed replacement part.

NOTE: While most EPR glassware is made from quartz, a few variable temperature components are actually made from Pyrex. Please note the material when ordering.

 

EPR電子順磁共振儀耗材 Dewar Flasks (Cold-Finger Dewars)

EPR電子順磁共振儀耗材
Impurity Analyses – Clear Fused Quartz (CFQ) vs. Suprasil (Synthetic Quartz)      
EPR Sample Tubes and Accessories    
EPR Cells    
Dewar Inserts    
‧ Dewar Flasks (Cold-Finger Dewars)  
Variable Temperature Accessories      
Electrolytic Cells for EPR     
Miscellaneous EPR Supplies    

Dewar Flasks (Cold-Finger Dewars)
•Large Nitrogen Dewar Flasks
•Liquid Nitrogen Dewar Flask

Large Nitrogen Dewar Flasks

Want the easiest way to take your samples to liquid nitrogen temperatures?
Dewar Flasks provide you with a convenient alternative to VT systems for studies at -195°C. Wilmad makes flasks for almost all common cavity resonators including those requiring reservoirs “off-set” from the center axis. Use these for cavities with iris controls near the Dewar Flask reservoir. Select either Clear Fused Quartz (CFQ) or Suprasil “cold-fingers.” All Dewar Flasks are silvered about the reservoir. Each Dewar Flask is shipped with protective nylon meshing.

Large 150mL Dewar Flasks
For longer experiments (25-45 minute sample immersion), part number WG-853 series are for resonators requiring reservoirs ‘off-set’ from the center axis.
***Special Note: Not recommended for contemporary EPR.

Small 50mL Dewar Flasks
When you have plenty of sample signal and experiments take only 15-25 minutes, these small Dewar Flasks are ideal. They can handle up to 4mm OD sample tubes or solid samples mounted onto the end of 4mm OD quartz rods. WG-819s are for resonators requiring reservoirs ‘off-set’ from the center axis.

Technical Tip:
Keeping Dewar Flask reservoirs and “cold-fingers” clean will extend the hold time by reducing the rate of nitrogen boil.

Remember!
Wilmad uses “-Q” to designate versions using Suprasil in the critical portions of the cell. All other cells are prepared from Clear Fused Quartz (CFQ).

Liquid Nitrogen Dewar Flask

Liquid nitrogen is an easily transported and economic source of coolant, whose boiling point is far below the freezing point of water without pressurization. This unique feature makes it useful for a wide range of applications in basic science research such as cell cryopreservation, sample degasification by freeze-pump-thaw cycle and cold trap for experiments involving vacuum lines.

Continuing our goal to remain the world’s leading provider of NMR and EPR consumables and accessories we’ve added a high quality Liquid Nitrogen Dewar Flask for these applications.

Highlights:

~30% cheaper but with equal or better quality than major manufacturers’ corresponding products

~Highly vacuumed (<10-6 torr) and fully silvered cylindrical Dewar minimizes liquid nitrogen loss during storage
~Unique 3 inch aluminum base increases stability
~Better protection for the vacuum hose
~Supplied with Black Ethafoam Stopper

EPR電子順磁共振儀耗材 Dewar Inserts

EPR電子順磁共振儀耗材
Impurity Analyses – Clear Fused Quartz (CFQ) vs. Suprasil (Synthetic Quartz)   
EPR Sample Tubes and Accessories    
EPR Cells   
‧ Dewar Inserts  
Dewar Flasks (Cold-Finger Dewars)   
Variable Temperature Accessories    
Electrolytic Cells for EPR    
Miscellaneous EPR Supplies    

Dewar Inserts
•Standard VT Dewar Inserts
•Simple Dewar Inserts
•JEOL Dewar Inserts
•Dewar Insert for Q-Band or Loop Gap Resonators
•Dewar Insert for TM Aqueous Cell
•High Temperature Dewar Inserts

Standard VT Dewar Inserts

These are the most common Dewar Inserts in EPR!
WG-821 and WG-822 Dewar Inserts
Sample tubes 4mm in diameter can be used with any of these Dewar inserts. You can use 5mm tubes in those with “-F” in the product number.

Standard Length Dewar Inserts

Long Dewar Inserts

NOTE: If you need a Dewar Insert with a different diameter or length, with silvering or dimples, please contact us. Wilmad has made many modified Dewar Inserts for spectroscopists like you. Just send us information about your requirements.

Remember!
Wilmad uses “-Q” to designate versions using Suprasil in the critical portions of the cell. All other cells are prepared from Clear Fused Quartz (CFQ).

Simple Dewar Inserts

Need a simple Dewar Insert for your research?

WG-824 and WG-826 Dewar Inserts

Sample tubes 4mm in diameter can be used with any of these Dewar inserts. You can use 5mm tubes in those with “-F” in the product number.

NOTE: If you need a Dewar Insert with a different diameter or length, with silvering or dimples, please contact us. Wilmad has made many modified Dewar Inserts for spectroscopists like you. Just send us information about your requirements.

Remember!
Wilmad uses “-Q” to designate versions using Suprasil in the critical portions of the cell. All other cells are prepared from Clear Fused Quartz (CFQ).

JEOL Dewar Inserts

Why pay more for a replacement JEOL Dewar Insert?

Sample tubes 4 or 5mm in diameter can be used with the JEOL dewar inserts. Sample support dimples can be added, if needed.

Remember!
Wilmad uses “-Q” to designate versions using Suprasil in the critical portions of the cell. All other cells are prepared from Clear Fused Quartz (CFQ).

Dewar Insert for Q-Band or Loop Gap Resonators

Control temperature inside small Q-Band or Loop-Gap resonators.
WG-894 Dewar Insert

You can control the temperature of samples in small resonators by putting the entire resonator in Wilmad’s largest Dewar Insert.

Dewar Insert for TM Aqueous Cell

TM110Aqueous Cell Dewar Insert

To control your sample temperature near ambient in TM Aqueous Cells, use Wilmad’s WG-821-TMR Dewar Insert.

NOTE: Control the temperature of a TM Aqueous Cell near room temperature with this special insert; the upper section is not dewared.

High Temperature Dewar Inserts

At temperatures higher than 300 degrees Celsius, cavity heating is a problem with standard Dewar Inserts. But Wilmad’s WG-821-HT gives you a solution.

Sample tubes up to 4mm in diameter can be used with any ot these high-temperature dewar inserts.

NOTE: Wilmad does not offer a Dewar Insert for the Bruker ER4111HT High Temperature Cavity Resonator system.